Product ID:ALODINE 1201
MSDS Date:08/16/1998
FSC:8030
NIIN:00-823-8039
MSDS Number: CLMFR

RALRUBE INC.

36977 FOX GLEN
FARMINGTON HILLS, MI 48331
US

Emergency Phone: 248-661-0260

Info Phone: 248-661-0260, FAX 248-661-3941

Cage: 6X798

RALRUBE INC.

FARMINGTON HILLS, MI 48331 US

Telephone: 248-661-0260, FAX 248-661-3941

Cage: 6X798

HYDROFLUORIC ACID

CAS: 7664-39-3

RTECS: MW7875000

OSHA PEL C 3 PPM AS F

ACGIH TLV: C 3 PPM AS F

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

CHROMIC ACID

CAS: 7738-94-5

RTECS: GB2450000

OSHA PEL 0.1 MG/M3

ACGIH TLV: 0.05 MG/M3

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

POTASSIUM FERRICYANIDE

CAS: 13746-66-2

RTECS: LJ8225000

OSHA PEL NONE

ACGIH TLV: NONE

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYES: CONTACT WITH EYES CAN CAUSE
SEVERE IRRITATION. SKIN CONTACT: CONTACT WITH SKIN CAN CAUSE
IRRITATION. CONTACT WITH SKIN CAN CAUSE SEVERE BURNS WHICH MAY NOT
BE IMMEDIATELY PAINFUL OR VISIBLE. S KIN ABSORPTION: CHROMIC ACID
MAY BE ABSORBED THROUGH SKIN, ESPECIALLY IF SKIN IS DAMAGED. FATAL
KIDNEY DAMAGE WAS REPORTED IN A PERSON WHO EVIDENTLY ABSORBED
CHROMIUM TRIOXIDE INTO THE BODY. INGESTIO N: NO INFORMATION
AVAILABLE. INHALATION: CAN CAUSE IRRITATION OF UPPER RESPIRATORY
TRACT AND ULCERATION OF MUCOUS MEMBRANES.
Explanation of Carcinogenicity:CARCINOGEN - CONTAINS CHROMIC ACID.
CHROMIUM VI AND IT'S COMPOUNDS: IARC GROUP 1, VOLUME 49, PAGE 49,
1990. NTP 9TH ANNUAL REPORT KNOWN TO BE HUMAN CARCINOGENS LIST.

First Aid:INGESTION: CONTACT A PHYSICIAN IMMEDIATELY . INHALATION:
REMOVE TO FRESH AIR. SUPPORT BREATHING. CONTACT A PHYSICIAN
IMMEDIATELY . EYE CONTACT: IMMEDIATELY FLUSH EYES WITH POTABLE
WATER FO R A MINIMUM OF 15 MINUTES. CONTACT A PHYSICIAN . SKIN
CONTACT: FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15
MINUTES. REMOVE CONTAMINATED CLOTHING. CONTACT A PHYSICIAN .

Extinguishing Media:AS REQUIRED TO EXTINGUISH SURROUNDING FIRE.
Fire Fighting Procedures:WEAR POSITIVE PRESSURE SELF-CONTAINED
BREATHING APPARATUS (NIOSH APPROVED - ) AND FULL PROTECTIVE
CLOTHING.
Unusual Fire/Explosion Hazard:PRESENTS NO HAZARD IN LIQUID FORM,
HOWEVER CHEMICAL CONTAINS STRONG OXIDIZERS WHICH MAY SUPPLY OXYGEN
WHEN DRY.

Spill Release Procedures:WEAR PROTECTIVE CLOTHING. ABSORB OR OTHERWISE
COLLECT SPILL AND STORE IN POLYETHYLENE OR POLYETHYLENE-LINED STEEL
CONTAINER.

Handling and Storage Precautions:DO NOT GET IN EYES, ON SKIN OR ON
CLOTHING. CLOTHING OR OTHER COMBUSTIBLE MATERIAL WET WITH THIS
MATERIAL AND ALLOWED TO DRY MAY BECOME FLAMMABLE. WASH THOROUGHLY
AFTER HANDLING. FOR INDUSTRIAL USE ON LY.
Other Precautions:EMERGENCY OVERVIEW: CONTACT CAN CAUSE SEVERE EYE
IRRITATION. CAN CAUSE SKIN IRRITATION. CARCINOGEN - CONTAINS
CHROMIC ACID.

Respiratory Protection:IF VAPORS OR MIST ARE GENERATED WEAR A NIOSH
APPROVED RESPIRATOR.
Ventilation:USE WITH ADEQUATE VENTILATION. PROVIDE GENERAL AND LOCAL
EXHAUST VENTILATION.
Protective Gloves:WEAR CHEMICAL RESISTANT GLOVES SUCH AS NEOPRENE, PVC,
BUTYL RUBBER.
Eye Protection:(ANSI APPROVED - ) CHEMICAL GOGGLES OR FACE SHEILD (&
SAFETY GLASSES - FPN)
Other Protective Equipment:WEAR PROTECTIVE CLOTHING SUCH AS RUBBER
APRONS, BOOTS AS NECESSARY TO AVOID SKIN CONTACT. EYE WASH FACILITY
AND EMERGENCY SHOWER (MEETING ANSI DESIGN CRITERIA - ) SHOULD BE IN
CLOSE PROXIMITY.
Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING,
DRINKING, SMOKING OR USING TOILET. LAUNDER CONTAMINATED CLOTHES
BEFORE REUSE .
Supplemental Safety and Health
DO NOT GET IN EYES, ON SKIN OR ON CLOTHING.

Boiling Pt:=100.C, 212.F
Vapor Density:NOT APPLIC
Spec Gravity:1.0 - 1.1
pH:< 2
Evaporation Rate & Reference:NOT DETERMINED
Solubility in Water:COMPLETE
Appearance and Odor:AMBER LIQUID; NO ODOR.
Percent Volatiles by Volume:NOT APPLIC

Stability Indicator/Materials to Avoid:YES
KEEP SEPARATE FROM ALKALIES.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:CONTAINS LESS THAN 1% POTASSIUM
FERRICYANIDE. WHEN HEATED TO DECOMPOSITION OR ON CONTACT WITH
STRONG ACIDS POTASSIUM FERRICYANIDE CAN EMIT FUMES OF CYANIDE.

Waste Disposal Methods:THIS CHEMICAL CONTAINS CHROMIUM COMPOUNDS AND
FLUORIDE COMPOUNDS. WASTE TREATMENT AND NEUTRALIZATION MAY BE
REQUIRED PRIOR TO DISCHARGE TO A SEWER. DISPOSE OF IN COMPLIANCE
WITH ALL APPLICABLE FEDERA L, STATE AND LOCAL REGULATIONS.

Toxicological Information:CHROMIC ACID: ORAL RAT LD50: 80 MG/KG.
POTASSIUM FERRICYANIDE: ORAL RAT LDL0: 1600 MG/KG. HYDROFLUORIC
ACID: INHALATION LC50: 966 PPM/1 HR.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NO INFORMATION AVAILABLE.

Transport Information:DOT SHIPPING NAME: NOT DOT REGULATED. CONTAINS
CLAUSE: N/A. UN / NA NUMBER: N/A. CLASS: N/A. PACKAGING
GROUP: N/A. PRODUCT RQ (LBS): N/A. RQ CLAUSE: N/A. NOTE: RQ
INFORMATION IS BASED ON A 55-GAL CONTAINER SIZE. PLEASE REFER TO
THE PRODUCT LABEL FOR RQ ON OTHER SIZE CONTAINERS.

SARA Title III Information:SEC 302 EHS: HYDROFLUORIC ACID - YES,
CHROMIC ACID - NO, POTASSIUM FERRICYANIDE - NO. SEC 313 LIST:
HYDROFLUORIC ACID - YES, CHROMIC ACID - YES, POTASSIUM FERRICYANIDE
- NO.
Federal Regulatory Information:CERCLA LIST: HYDROFLUORIC ACID - YES,
CHROMIC ACID - YES, POTASSIUM FERRICYANIDE - NO. COMPONENTS OF
THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY. EPA REACTIVE
HAZARD: NO. EPA SUDDEN RELEASE OF PRESSURE: NO. FIRE HAZARD:
NO. EPA IMMEDIATE HEALTH HAZARD: YES. EPA DELAYED HEALTH
HAZARD: YES.
State Regulatory Information:CALIFORNIA PROPOSITION 65: WARNING: THIS
PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER.